When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | (CH3)PH2_Halmann(1963)_296K_185-210nm(meas).txt |
NAME: | methylphosphine |
FORMULA: | (CH3)PH2 |
AUTHOR(YEAR): | Halmann(1963) |
T: | 296K |
λ: | 185-210nm(meas) |
BIBLIOGRAPHY: |
M. Halmann, "Far-ultraviolet absorption spectra of phosphorous compounds in the gas phase",
J. Chem. Soc. 1963, 2853-2856 (1963);
DOI: 10.1039/JR9630002853
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COMMENTS: | Absorption measurements using Beckman, Hilger, Cary, and Unicam spectrophotometers
The data points plotted in Fig. 1 (extinction coefficients vs. wavelength) have been digitized and the extinction coefficients have been converted to absorption cross sections (conversion factor 3.8235×10-21) For the absorption maxima at 187 and 201 nm the extinction coefficients εmax =1500 ± 200 and 130 ± 30 L mole-1 cm-1 are reported, which correspond to σmax = (5.7 ± 0.8)×10-18 and (5.0 ± 1.1)×10-19 cm2 molecule-1 |
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